Conditioners

Guar hydroxypropyltrimonium chloride

INCI: GUAR HYDROXYPROPYLTRIMONIUM CHLORIDE · also Cationic guar

The conditioning polymer that works from inside a shampoo.

How common

All products5.1%
In shampoos30%
In conditioners13%
In hair colours5.9%

758 of 14,784 products with a full ingredient list in Open Beauty Facts; No. 54 of all the names found on their labels.

What it is

  • Cationic guar: a polysaccharide (a long sugar chain) carrying positive charges.

    SourceHide
    Cationic guar is an important polysaccharide used as a hair conditioning agent in personal care products.[1] Study · 2021 · open source

Why it is in products

  • To condition hair from a shampoo. It is one of the standard conditioning polymers that new ones are measured against.

    2 sourcesHide
    Cationic guar is an important polysaccharide used as a hair conditioning agent in personal care products.[1] Study · 2021 · open source
    Commercial conditioning polymers: Polyquaternium-10 (PQ-10) (UCARE Polymer LR-30M) and Guar Hydroxypro-pyltrimethylammonium Chloride (Jaguar C-13S) were used as performance benchmarks.[2] Study · 2004 · open source

What it does

  • It sticks to hair by its charge and leaves a layer on the surface; the polymer’s size (molecular weight) largely sets how thick the layer is.

    Some evidencehair2 sourcesHide
    as it interacts electrostatically with hair[1] Study · 2021 · open source
    The MW of the cationic guar variants plays an integral role in determining the thickness of the adsorbed polymer layer on the hair surface[1] Study · 2021 · open source

Where it works

Surface (cuticle)Inside (cortex)Core (medulla)

On the hair’s surface, as a thin polymer layer.

Some evidenceSourceHide
the thickness of the adsorbed polymer layer on the hair surface[1] Study · 2021 · open source

Rules

European Union

  • No EU limit: it is not on the regulation’s lists of banned or restricted substances, preservatives or UV filters.

    How we checkedHide
    We searched Annexes II to VI of the EU regulation (consolidated text of 18 May 2026): no entry.open the list

United States

  • Not on the FDA’s list of prohibited or restricted cosmetic ingredients. In the US, cosmetics and their ingredients (other than colour additives) don’t need FDA approval before sale.

    SourceHide
    Under U.S. law, cosmetic products and ingredients, other than color additives, do not need FDA approval before they go on the market[3] US Food and Drug Administration · open source
    We searched the FDA’s list of prohibited and restricted cosmetic ingredients: no entry.open the list

Sources

  1. Investigation of the interactions of cationic guar with human hair by electrokinetic analysis McMullen RL et al., International journal of cosmetic science, 2021StudyAuthors include staff of Ashland
  2. Effects of low-level hydrophobic substitution on conditioning properties of cationic cellulosic polymers in shampoo systems Drovetskaya TV et al., Journal of cosmetic science, 2004StudyAuthors include staff of Amerchol (Dow)
  3. Prohibited & Restricted Ingredients in Cosmetics | FDA US Food and Drug Administration

Checked against these sources on 4 November 2026. Spot a mistake? Tell us.